Nixene Journal Volume 9 Issue 5 Article 37

Regular readers will be aware of my view that the field of graphene is moving faster than anyone realises. More evidence supporting this emerged this month. A team at Penn State university in the USA has been working on experiments with passing sound waves through sheets of graphene with precise holes drilled in hexagonal patterns. They made the acoustic analogue of twisted bilayer graphene and found the acoustic equivalent of the magic angle. So, as well as twistronics for electrons we now have phononics for sound waves in twisted bilayer graphene, and probably other 2D materials. A new field of scientific study made possible by graphene the progress really is astonishing. The US Government is starting to wake up to the power of graphene. James Tour’s flash graphene is attracting the attention. The team now can take the waste char from plastic recycling and turn it in to graphene that improves the strength of cement by 30%. Rice University says the Air Force Office of Scientific Research and the Department of Energy supported the research. Trade magazines in the construction sector are also picking up on this. Another development by James Tour; Laser induced graphene is being used to make biosensors that detect and diagnose SARS-CoV-2 in blood and saliva samples. The test links to a smartphone and produces results in ten minutes. More work is being done with graphene supercapacitors. It looks like increasing the surface area of graphene nanoplates by increasing the separation between the nanoplates increases the energy density. Cross linking the nanoplates with a big molecule that is also electrically conductive improves the supercapacitor performance still further. Computer graphics card manufacturer, Gigabyte, has launched a new high end gaming card. Graphene is being used to improve the cooling performance, interestingly not using the thermal properties, but using graphene as a lubricant. Investors seem to be taking a more active interest in graphene companies. Ionic, the Australian supercapacitor manufacturer has received $2million to develop its manufacturing operation. In the UK Versarien has raised another £3.5million and Applied Graphene Materials has raised £6million in cash by selling more shares. This gives both companies some financial breathing room but also raises the pressure to deliver revenue growth. And there is lots more of interest in this packed issue. Adrian Nixon, 1st February 2021

A graphene toaster was demonstrated for the first time at the consumer electronics show in Las Vegas by Korean company Graphene Square. This may not sound like a world changing invention, but it is something worth paying attention to because this is a rare application for chemical vapour deposition (CVD) graphene in a consumer electronics device. Until now, CVD graphene has been used in very small pieces in sensors. This toaster has a piece of CVD graphene on the top and bottom glass panels making a transparent infrared grill. The graphene is made at a scale of 200mm x 150mm and this tells us a that the company has a viable CVD roll to roll process. The process can make graphene at this scale and also provides the capability to separate the graphene from the forming substrate to other surfaces, in this case glass. The next step is to do this commercially. Graphene Square admits this is still at least a year away. This is still impressive progress and tells us that the industrial manufacture of CVD graphene is developing quickly. CVD graphene is also in the news this month. British company Paragraf announced through Queen Mary University, London, that they can create graphene at wafer scale, and this could be a replacement for indium tin oxide (ITO). This was picked up by technology blogs around the world, and graphene manufacturer Versarien felt obliged to disclose it is working on a similar project with a graphene manufacturer in Korea. These announcements about CVD graphene touchscreens sound impressive. However, as far as we can tell from the current state of the art, the economic and technical cases are not sufficiently proven to convince us we will see this technology in the immediate future. The term ‘bottom-up graphene’ used to refer to CVD graphene assembled atom by atom. Graphene powder manufacturing has been evolving rapidly over the last few years and can now be made by atomic assembly methods too. We have summarised the various methods in our special feature. We also look at the implications for competitive activity, as these new manufacturing methods meet the new market dynamics driving the sustainability agenda. While we cannot state which individual companies will achieve success, we can make some predictions about the characteristics successful graphene powder manufacturers will need to have. We hope you agree this makes for fascinating reading along with the rest of the compelling content this issue. Adrian Nixon, 1st February 2022