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Vol 6 Issue 5
Over the past five years, we have been paying attention to how graphene can improve battery technology. The market focus has been on batteries for electric vehicles. Graphene has been used in the electrodes, and this has made improvements in charging time and battery life. However, energy density has not been improved. Energy density is the amount of energy that can be squeezed into a given volume or mass. This is important for electric vehicles because the higher the energy density, the further a vehicle can travel for a given quantity of batteries. MIT have been paying attention to this battery development dynamic. A spin out company from the university called PolyJoule has developed a new battery (p. 21). This has even poorer energy density, one fifth that of lithium-ion technology, so this is not going to be used for electric vehicles. The MIT researchers have spotted another market – grid storage. These new batteries appear to be ideal for grid storage applications. They charge and discharge rapidly have a long battery life, do not require cooling, and do not need lithium and toxic heavy metals. These batteries are a new intermediate-type between lithium ion and lead-acid technology. We will pay closer attention to this company in the future because storing electricity from renewables such as wind and solar power requires effective grid storage batteries. Also in this issue, Debbie interviewed the CEO of Ceylon Graphene Technologies. This company has local access to some of the highest quality graphite in the world and is very well equipped to process and develop this into high quality graphene powders (p. 7). The company is actively working on new products and extending the value chain towards the market applications. It will be fascinating to see the results of this activity in the market in the coming years. Yet more fascinating research is being published. You may recall that Debbie met Chris Griggs and Sarah Grace Zetterholm of the US Army ERDC (Vol 5 iss 12, p.10). Their team has developed a graphene filter that removes the toxin produced by algal blooms. This filter cleans up poisoned water that is harmful to humans and fish(p.13) Staying with the biology theme, researchers in the Netherlands have developed a graphene sensor that can listen to the sounds made by individual bacteria. This sensor could find uses exploring the effectiveness of antibiotics with unprecedented precision. Another team in the Netherlands has been developing graphene sensors for testing in space. SpaceX launched these sensors this month. The sensors are now approaching a sun synchronous orbit where their performance will be evaluated. Graphene really is out of this world, and as usual there is so much more to read in this issue. Adrian Nixon, 1st May 2022£45.00 View product -
Vol 5 Issue 8
I have learned that news headlines which end with a question mark are nearly always less interesting than those that do not. A case in point: An article was posted at the start of the month asking “Has the funding for graphene dried up?” (p.48). On the same day, Estonian graphene supercapacitor manufacturer Skeleton announced it has secured over €120million in funding over the past 12 months (p.49). This probably makes Skeleton the most commercially successful application for graphene so far. Other companies prefer to avoid the limelight and operate in secret until they are ready to come out into the open. Sometimes their public disclosure is deliberate. Charmgraphene announced this month they are in the roll-to-roll graphene manufacturing business and can make graphene at speeds of 2m per minute and lengths up to 1km (p.36). Sometimes the disclosure is accidental, as might be the case with an academic paper being published by one of the researchers working with graphene photonics company CamGraPhIC (p.21 and p.33). We don’t need to be as concerned with secrecy, quite the reverse. Our purpose is to inform you of the activity we are monitoring in this fast-moving field, special features are part of the way we do this. This issue is the first time Debbie, Rob and I have all written special features in one edition. Debbie has been interviewing Graphene Star. They have developed a very high solids content (25% solids) graphene dispersion that is water based and appears to be very stable. The company has been creating novel coatings with a traditional paint company in the UK. The combination of the old and new seems to be working well for both companies. My contribution is a look at the state of the art of industrial CVD graphene manufacturing. If you ever wondered what the ‘Market, Application and Product Type’ keywords tables are for, then Rob’s special feature will give you part of the answer. We are creating a structured keyword database that builds with each journal issue. This is primary data; you will not find this anywhere else. Rob has been analysing the instances of our keywords over time to explore the market application trends for graphene products since 2017. The results are revealing and show where the global applications development has been and will be for the near future. And, in case you were wondering, yes, Rob’s analysis does include supercapacitors. This appears in the top ten of applications. Dear Reader, we have done more sorting of the signal from the noise, as usual there is so much more to read in this issue. Adrian Nixon, 1st August 2021£45.00 View product -
Vol 7 Issue 1
Batteries feature several times in this issue of the journal. Dear Reader, you will know that energy density is the key performance metric we watch. The higher the energy density (Wh/kg) the further you can travel on a battery charge. Current lithium-ion (Li-ion) batteries have an energy density around 260Wh/kg. We have highlighted the work of a company developing lithium-sulphur technology (Li-S) vol 5 iss 12 p.35. They have claimed energy densities over three times that of current Li-ion batteries using graphene enhanced cell designs. You will probably guess that we have been following this company and contacted them multiple times. We have yet to see data to back up these extraordinary claims. It was with interest that we found an online discussion between battery experts, the consensus view is that Li-S technology can create higher energy densities than Li-ion. However, this comes at a cost of reduced battery life. Perhaps this is the reason we have yet to see data backing up the claims for Li-S technology. Then NASA announced they have been working on a new graphene enhanced battery technology. The graphene is used as the structure for a sulphur/selenium cathode and is based on holey graphene that NASA developed in 2017. A solid-state electrolyte separates the anode from a lithium metal anode. The interim results are promising. They have achieved an energy density of 500Wh/kg. The battery seems to be safer too. It resists impact damage and has a maximum operating temperature of 150°C. NASA anticipates this solid-state battery will start to become available within three to five years. Elsewhere in this issue we report on developments as diverse as graphene enhanced condoms in India to graphene enhanced polymers launched on a SpaceX rocket bound for the moon. There is so much more in between these two very different applications, I encourage you to read on… Adrian Nixon 1st January 2023£45.00 View product -
Vol 5 Issue 12
Two new graphene companies have appeared on the radar this month. They both use a similar process to make graphene from methane gas with hydrogen as a by-product. Looking at the patents of the companies they both use a microwave reactor to tear apart the carbon and hydrogen atoms in methane, the carbon atoms recombine as graphene and the hydrogen atoms recombine to form hydrogen gas. There the similarities pause because the two companies have very different approaches for how to market their developments. The first company is Levidian, they are a relaunch of Cambridge Nanosystems from the UK. Their business model is focussed on using waste methane gas from a customer’s process. They use the reactor to lock up the carbon in the methane as graphene and claim carbon capture credits. The graphene production is secondary to this marketing approach. Using disclosures by the company, I was able to create a mass balance for the Levidian method. It appears that the process captures carbon from methane with around 30% efficiency (p.34). Not bad, but still some further progress to make. The second company is California based Lyten who publicly disclosed their activity just a few weeks ago. They were formed in 2015 and have been operating in stealth mode. Their graphene is used to make the electrode for a lithium sulphur (LiS) battery that has three times the energy density of normal lithium-ion batteries (p.35). They have probably decided to come out of stealth mode to raise capital for the scaling up of their process. The company is currently talking with five original equipment manufacturers (OEMs) in the automobile industry. The weakness of LiS batteries has been their capacity fade with repeated charge / discharge cycles. Lyten say they have improved on previous LiS designs so they might have something of interest for manufacturers of electric vehicles. Levidian patented their process in 2014 and Lyten in 2015. Lyten references the Levidian patents in their applications. This is how we know the two processes are very similar. Things could get interesting if one or the other company makes a lot of money in the future. As Elon Musk observed “A patent is like buying a lottery ticket to a lawsuit”. Staying with graphene powder manufacture, we feature John van Leeuwen of Universal Matter in a special feature (p.7). He is leading the drive to scale up the flash graphene process developed by Prof James Tour at Rice University. Universal Matter is definitely a company to watch in the future. All these graphene manufacturing processes are bottom-up, self-assembling graphene atom by atom to create high quality powders. These processes are in their infancy at present. If they can be scaled, they could disrupt the graphene-from-graphite manufacturers in future as they promise controllable quality graphene. This potential market disruption is something we’ll explore in the future, in the meantime there is much more to explore in this issue… Adrian Nixon, 1st December 2021£45.00 View product