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Vol 6 Issue 2
A graphene toaster was demonstrated for the first time at the consumer electronics show in Las Vegas by Korean company Graphene Square. This may not sound like a world changing invention, but it is something worth paying attention to because this is a rare application for chemical vapour deposition (CVD) graphene in a consumer electronics device. Until now, CVD graphene has been used in very small pieces in sensors. This toaster has a piece of CVD graphene on the top and bottom glass panels making a transparent infrared grill. The graphene is made at a scale of 200mm x 150mm and this tells us a that the company has a viable CVD roll to roll process. The process can make graphene at this scale and also provides the capability to separate the graphene from the forming substrate to other surfaces, in this case glass. The next step is to do this commercially. Graphene Square admits this is still at least a year away. This is still impressive progress and tells us that the industrial manufacture of CVD graphene is developing quickly. CVD graphene is also in the news this month. British company Paragraf announced through Queen Mary University, London, that they can create graphene at wafer scale, and this could be a replacement for indium tin oxide (ITO). This was picked up by technology blogs around the world, and graphene manufacturer Versarien felt obliged to disclose it is working on a similar project with a graphene manufacturer in Korea. These announcements about CVD graphene touchscreens sound impressive. However, as far as we can tell from the current state of the art, the economic and technical cases are not sufficiently proven to convince us we will see this technology in the immediate future. The term ‘bottom-up graphene’ used to refer to CVD graphene assembled atom by atom. Graphene powder manufacturing has been evolving rapidly over the last few years and can now be made by atomic assembly methods too. We have summarised the various methods in our special feature. We also look at the implications for competitive activity, as these new manufacturing methods meet the new market dynamics driving the sustainability agenda. While we cannot state which individual companies will achieve success, we can make some predictions about the characteristics successful graphene powder manufacturers will need to have. We hope you agree this makes for fascinating reading along with the rest of the compelling content this issue. Adrian Nixon, 1st February 2022£45.00 View product -
Vol 5 Issue 9
At the time of writing the Paralympic games are still in progress in Tokyo. The able-bodied Olympic games in Tokyo has ended and details of the technology behind some of the medal winning performances has leaked out. Graphene has been playing a role in these games. The gold medal for archery was won by Korea with their athlete using graphene from Standard Graphene to enhance the polymer composite bow. The Women’s cycling produced two gold medals for the Netherlands with the winner using Directa Plus graphene ink in the clothing to maintain optimum heating. Haydale worked with the British team to create a similar wearable technology with its graphene inks for British medal winners. The technology is secret at the moment but we can expect a trickle-down effect to spread graphene further out into the sports market. We have three special features this month. Our Women in Graphene series continues. Debbie an interviewed Akanksha Urade, from India. We noticed Akanksha’s work on our social media feeds, she has a gift for explaining complex subjects in a clear and concise way that shows she really understands the science. This matches our ABC approach (p.6) and we respect her talents, well worth a read. Debbie also interviewed Dr. Chris Griggs of the US Army ERDC. They have been excited about the potential for graphene for some time now and are actively exploring several avenues of development. They are working with Universal Matter who are developing the flash graphene process from Prof James Tour’s lab at Rice University. They also have a strong interest in the removal of toxins from wastewater and they have an increasing interest in graphene and infrastructure applications, particularly with concrete and asphalt. I interviewed the leadership team behind the world’s first application of unreinforced graphene enhanced concrete. The GEIC and Nationwide Engineering have made a quantum leap in the application of this technology that they call Concretene. Concrete can not only be made stronger, so less is used, but graphene also helps the concrete achieve its final strength much faster than anyone expected. We suspect there are more benefits waiting to be discovered from these trials. There is so much more happening in the world of graphene and 2D materials this month. I have run out of space to summarise here so I’ll encourage you to dive into this packed issue and explore further. Adrian Nixon, 1st September 2021£45.00 View product -
Vol 5 Issue 1
In a previous life I led the market intelligence gathering and analysis for a large international company. I discovered that a good way to find out what the competition and customer organisations would do in the future was to look at the influence the corporate leader had on his or her company. Two new top appointments have been announced this month. First Graphene has a new Chief Executive Officer (CEO) with sales, marketing and growth expertise. Zen has a new CEO and also a Chairman, with skills acquired in financial management and investor relations. It will be interesting to observe the corporate behaviour of these two companies over the coming years. If the skills set of the leadership is a guide then we can expect that by this time next year First Graphene will generate its income from increased sales in diverse markets through organic growth and Zen will have raised more money from a variety of institutional sources focussed on their anti-viral graphene. We’ll watch both companies with interest. Graphene is still throwing up surprises in fundamental science: Andre Geim’s team at the University of Manchester continues to create high quality research. The latest paper in nature explores the way water condenses to a liquid from a vapour inside nanocapillaries made in two dimensional materials. The team showed that as the humidity rises to 80% water suddenly condenses out as a liquid and fills the nanocapillaries. This work may also mean that other graphene surfaces could be affected in a similar way by high levels of humidity suddenly transitioning to a liquid coating. Designers of graphene sensors for the internet of things may want to bear this in mind. A team at Princeton University in the USA has been exploring the source of superconductivity in twisted bilayer graphene. They found topological quantum states were created by the magic angle twist which forces the electrons to be at the same energy (a flat band). This creates regions that have electrically insulating interiors but the edges allow electrons to flow freely even if there are imperfections present in the material. At low temperatures and mild magnetic fields, the edges form stable superconducting channels throughout the material. These topological quantum states were a surprise discovery and will keep researchers busy for some time to come. And another team in China has created a new method for making graphene from waste plastic using microwave sintering. This shows that graphene will spontaneously form when carbon atoms are ripped apart and allowed to reform in the absence of oxygen. It looks like we will not run out of graphene supplies any time soon. Further fascination can be found in Rob Whieldon’s special feature. Rob has analysed the market keywords we use to tag all the applications of graphene since we started in 2017. His feature is a must-read in this issue. Adrian Nixon, 4th January 2021£45.00 View product -
Vol 5 Issue 5
It is not every month that a new allotrope of carbon is announced. The last time this happened was back in 2019 when researchers in the UK and Switzerland made a ring of 18 atoms called cyclocarbon (Vol3 iss9 p.12). This month a joint team in Germany and Finland have made a flat sheet of carbon atoms with 4 6 and 8 rings. They call this new material a biphenylene network (BPN). This new material seems to be exciting the researchers because it exhibits metallic character. It also opens the door to explore other potential allotropes of carbon. Graphene-metal composites also make another appearance this month. Two Indian organisations have been working on aluminium-graphene composites (Al-G). Tirupati graphite says it has made an Al-G composite that has 95% the electrical conductivity of copper with the light weight of aluminium (although no has been presented yet). The Maharaja Agrasen University has published a peer reviewed paper showing that 1% graphene powder produced a 67% increase in the ultimate strength of the aluminium composite. A joint team in the Netherlands and Germany has made a Pirani pressure sensor from multilayer CVD graphene. It is not only 100 times smaller than the state-of-the-art sensors; it consumes a fraction of the power and is so sensitive it can detect different gas molecules. Aerospace and automotive applications abound. A new car company, Viritech, has announced it is building an electric supercar with a range of 800km and a top speed in excess of 300km/hr. The company has rejected batteries in favour of a hydrogen fuel cell to generate the electricity. The hydrogen storage tank is made from graphene enhanced carbon fibre and is an integral part of the chassis. Production is due to start in 2023. Graphene enhanced concrete made the headlines this month. British construction company Nationwide Engineering and the University of Manchester’s Graphene Engineering Innovation Centre (GEIC) have created graphene enhanced concrete for the whole floor of a new building in Amesbury, UK. As well as being a practical success in CO2 reduction the use of graphene has reduced the quantity of materials involved by 30% and potentially cut the costs between 10 and 20%. This will catch on. Adrian Nixon, 1st June 2021£45.00 View product