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Vol 6 Issue 5
Over the past five years, we have been paying attention to how graphene can improve battery technology. The market focus has been on batteries for electric vehicles. Graphene has been used in the electrodes, and this has made improvements in charging time and battery life. However, energy density has not been improved. Energy density is the amount of energy that can be squeezed into a given volume or mass. This is important for electric vehicles because the higher the energy density, the further a vehicle can travel for a given quantity of batteries. MIT have been paying attention to this battery development dynamic. A spin out company from the university called PolyJoule has developed a new battery (p. 21). This has even poorer energy density, one fifth that of lithium-ion technology, so this is not going to be used for electric vehicles. The MIT researchers have spotted another market – grid storage. These new batteries appear to be ideal for grid storage applications. They charge and discharge rapidly have a long battery life, do not require cooling, and do not need lithium and toxic heavy metals. These batteries are a new intermediate-type between lithium ion and lead-acid technology. We will pay closer attention to this company in the future because storing electricity from renewables such as wind and solar power requires effective grid storage batteries. Also in this issue, Debbie interviewed the CEO of Ceylon Graphene Technologies. This company has local access to some of the highest quality graphite in the world and is very well equipped to process and develop this into high quality graphene powders (p. 7). The company is actively working on new products and extending the value chain towards the market applications. It will be fascinating to see the results of this activity in the market in the coming years. Yet more fascinating research is being published. You may recall that Debbie met Chris Griggs and Sarah Grace Zetterholm of the US Army ERDC (Vol 5 iss 12, p.10). Their team has developed a graphene filter that removes the toxin produced by algal blooms. This filter cleans up poisoned water that is harmful to humans and fish(p.13) Staying with the biology theme, researchers in the Netherlands have developed a graphene sensor that can listen to the sounds made by individual bacteria. This sensor could find uses exploring the effectiveness of antibiotics with unprecedented precision. Another team in the Netherlands has been developing graphene sensors for testing in space. SpaceX launched these sensors this month. The sensors are now approaching a sun synchronous orbit where their performance will be evaluated. Graphene really is out of this world, and as usual there is so much more to read in this issue. Adrian Nixon, 1st May 2022£45.00 View product -
Vol 6 Issue 8
Graphene enhanced concrete features several times this month. It seems that the world is starting to pick up on the environmental benefits. A new reservoir dam is under construction at Almudévar, northeast of Zaragoza in Spain. Graphenea and the University of Madrid have a graphene enhanced concrete trial on site. The trial is on non-structural components as you would expect for a new material on a critical project. The early results are showing that the addition of graphene will make the concrete last 50% longer. The Almudévar project would be notable just for this. What is interesting is the reaction of the leadership of the construction company, Lantania Group, building the dam. "This new additive is undoubtedly a step forward in improving the sustainability of infrastructures. By increasing its durability, we will be able to make concrete a more environmentally friendly material," Federico Ávila, President of Lantania When the top management of big construction companies start to make public statements like this, we know that things are starting to change. Another development with a sustainable theme is the industrial pilot scale recycling of end of life lithium-ion batteries from electric vehicles. The Hydrovolt plant in Norway can already recycle 12,000 tonnes of battery packs each year. The company reclaims 95% of the plastics and metals but the graphite electrodes were a waste stream. Graphmatech and Graphenea have collaborated to take the graphite waste and upcycle it into graphene oxide. This is a very encouraging development. Moving from graphene powders to large area sheet graphene, we have a special feature this month exploring the new material that will emerge in the foreseeable future. This is a Van der Waals homostructure of multi-layer large-area sheet single-crystal graphene. We propose a new name for this material; Graphene Super-Laminate (GSL). We will explore the properties of GSL in future issues, it promises to realise the full potential of graphene’s superlative properties. In this issue we start to see this new material being considered as the last piece of the puzzle for a world changing technology – the space elevator. Visions don’t come much bigger than this, and it just might be that graphene could play a key role in making this happen. You can find out about this and more in this issue, dear reader. Adrian Nixon 1st August 2022£45.00 View product -
Vol 6 Issue 4
We begin this month with a review of a new book by James Baker and James Tallentire – “Graphene: The Route to Commercialisation.” This book will be released later this month and well worth a read. It is part history of the graphene story and part how-to-guide to create a sustainable innovation ecosystem for new advanced materials. Graphene composites are making the news. The graphene-asphalt road trials in the UK have produced successful results. Oxfordshire County Council reports that graphene-enhanced asphalt improves the life of the road surface by 70%, and graphene enhances the stiffness of the surface, making it less prone to rutting. Another trial is underway on a 700m stretch of road with heavier traffic to see if similar benefits are reported. Korea is experimenting with graphene-metal composites to build new power lines for its electricity grid. The national power company announced a research project to enhance the power transmission capacity of the country’s energy distribution network. On a smaller scale, researchers in the USA are using graphene oxide scaffolds to create new bone using stem cells. Graphene oxide has been making more appearances on social media. Reuters felt compelled to investigate claims that graphene oxide was being put into ibuprofen tablets. Their conclusion was that these are false claims. Elsewhere, rather serious accusations are starting to emerge about one of Canada’s biggest graphene companies. Zentek (previously Zen Graphene Solutions) has been accused of unethical business practises. Prof. Rodney Ruoff’s group in Korea have been working with teams in Saudi Arabia and China to make large area single-crystal graphene. They used the chemical vapour deposition (CVD) process but allowed graphene to diffuse into the copper metal close to its melting point. This grew the graphene at the interface between the metal and a sapphire substrate. They added another clever step by diffusing nitrogen into the copper then rapidly heating the sample. This caused the nitrogen to expand, blowing off the copper, leaving the graphene exposed and undamaged. We can expect the team to speed up and scale up the process over the coming years. This team is one to watch. There are many more things to watch out for in this issue, dear reader. I will delay you no longer and let you dive into this month’s carefully curated content… Adrian Nixon, 1st April 2022£45.00 View product -
Vol 6 Issue 3
This month Rob and I gained first-hand experience of the benefits of adding graphene to enhance concrete. We were given a tour of the new Mayfield development in Manchester, UK. The site is still under construction, and parts of it are now open to the public. One of these areas is the new mezzanine floor area directly underneath the old Mayfield rail station. We were standing on what seemed to be an unremarkable concrete floor. It becomes remarkable when you know what to look for. We were lucky to have one of the joint MDs Alex McDermott as our guide. The whole floor was constructed and finished in a fraction of the time it would normally take. Also, the floor is flawless, with no expansion joints or cracking. There is also no sign of shrinkage. We knew graphene-enhanced concrete was strong. Now we know there are other benefits emerging. Graphene is the gift that keeps giving. Graphene-enhanced concrete is being trialled in other parts of the world too. In New Zealand, First Graphene has partnered with a particularly active distributor and trial pours are already underway. In the USA, Debbie discovered that the US Army ERDC also has an active interest in graphene enhanced concrete. They are discovering the same strength and fast cure benefits that graphene confers to the finished construction. You can find out more in her special feature. Battery technology continues to be developed. First Graphene and Zentek have both turned their attention to silicon anodes. Silicon is an attractive material to make Li-ion battery electrodes. The problem is it expands by up to 300% when lithium migrates into the crystal structure during charging. Using silicon particles coated with graphene nanoplates seems to mitigate this problem. Transition metal dichalcogenides (TMDs) are another two-dimensional (2D) material. Akanksha Urade wrote a good overview of the technology this month, and separately the Graphene Flagship published an overview of their interest in these materials. They have been working on using TMDs as next generation heat pumps. They can be used in heating and cooling applications and also as thermoelectric generators. This work is still at the early stage, however there are well funded teams working in this research area so we can expect to see meaningful progress in the future. Chemical vapour deposition (CVD) graphene used to be talked about in terms of just a research project. Now we know industrial processes can make graphene films by the kilometre and at high speeds. The development of the technology has matured from academia to industrial R&D. One of the companies in Korea, Charmgraphene has now developed graphene separation and transfer technology to the point where they can make freestanding graphene films at square centimetre scale and in thicknesses ranging from three to ten atomic layers thick. You can read about more of the astonishing progress being made in this field by reading this packed issue. Adrian Nixon, 1st March 2022£45.00 View product