Nixene Journal Volume 9 Issue 5 Article 25

Two new graphene companies have appeared on the radar this month. They both use a similar process to make graphene from methane gas with hydrogen as a by-product. Looking at the patents of the companies they both use a microwave reactor to tear apart the carbon and hydrogen atoms in methane, the carbon atoms recombine as graphene and the hydrogen atoms recombine to form hydrogen gas. There the similarities pause because the two companies have very different approaches for how to market their developments. The first company is Levidian, they are a relaunch of Cambridge Nanosystems from the UK. Their business model is focussed on using waste methane gas from a customer’s process. They use the reactor to lock up the carbon in the methane as graphene and claim carbon capture credits. The graphene production is secondary to this marketing approach. Using disclosures by the company, I was able to create a mass balance for the Levidian method. It appears that the process captures carbon from methane with around 30% efficiency (p.34). Not bad, but still some further progress to make. The second company is California based Lyten who publicly disclosed their activity just a few weeks ago. They were formed in 2015 and have been operating in stealth mode. Their graphene is used to make the electrode for a lithium sulphur (LiS) battery that has three times the energy density of normal lithium-ion batteries (p.35). They have probably decided to come out of stealth mode to raise capital for the scaling up of their process. The company is currently talking with five original equipment manufacturers (OEMs) in the automobile industry. The weakness of LiS batteries has been their capacity fade with repeated charge / discharge cycles. Lyten say they have improved on previous LiS designs so they might have something of interest for manufacturers of electric vehicles. Levidian patented their process in 2014 and Lyten in 2015. Lyten references the Levidian patents in their applications. This is how we know the two processes are very similar. Things could get interesting if one or the other company makes a lot of money in the future. As Elon Musk observed “A patent is like buying a lottery ticket to a lawsuit”. Staying with graphene powder manufacture, we feature John van Leeuwen of Universal Matter in a special feature (p.7). He is leading the drive to scale up the flash graphene process developed by Prof James Tour at Rice University. Universal Matter is definitely a company to watch in the future. All these graphene manufacturing processes are bottom-up, self-assembling graphene atom by atom to create high quality powders. These processes are in their infancy at present. If they can be scaled, they could disrupt the graphene-from-graphite manufacturers in future as they promise controllable quality graphene. This potential market disruption is something we’ll explore in the future, in the meantime there is much more to explore in this issue… Adrian Nixon, 1st December 2021

It is not every month that a new allotrope of carbon is announced. The last time this happened was back in 2019 when researchers in the UK and Switzerland made a ring of 18 atoms called cyclocarbon (Vol3 iss9 p.12). This month a joint team in Germany and Finland have made a flat sheet of carbon atoms with 4 6 and 8 rings. They call this new material a biphenylene network (BPN). This new material seems to be exciting the researchers because it exhibits metallic character. It also opens the door to explore other potential allotropes of carbon. Graphene-metal composites also make another appearance this month. Two Indian organisations have been working on aluminium-graphene composites (Al-G). Tirupati graphite says it has made an Al-G composite that has 95% the electrical conductivity of copper with the light weight of aluminium (although no has been presented yet). The Maharaja Agrasen University has published a peer reviewed paper showing that 1% graphene powder produced a 67% increase in the ultimate strength of the aluminium composite. A joint team in the Netherlands and Germany has made a Pirani pressure sensor from multilayer CVD graphene. It is not only 100 times smaller than the state-of-the-art sensors; it consumes a fraction of the power and is so sensitive it can detect different gas molecules. Aerospace and automotive applications abound. A new car company, Viritech, has announced it is building an electric supercar with a range of 800km and a top speed in excess of 300km/hr. The company has rejected batteries in favour of a hydrogen fuel cell to generate the electricity. The hydrogen storage tank is made from graphene enhanced carbon fibre and is an integral part of the chassis. Production is due to start in 2023. Graphene enhanced concrete made the headlines this month. British construction company Nationwide Engineering and the University of Manchester’s Graphene Engineering Innovation Centre (GEIC) have created graphene enhanced concrete for the whole floor of a new building in Amesbury, UK. As well as being a practical success in CO2 reduction the use of graphene has reduced the quantity of materials involved by 30% and potentially cut the costs between 10 and 20%. This will catch on. Adrian Nixon, 1st June 2021