Nixene Journal Volume 9 Issue 5 Article 16

Regular readers will be aware of my view that the field of graphene is moving faster than anyone realises. More evidence supporting this emerged this month. A team at Penn State university in the USA has been working on experiments with passing sound waves through sheets of graphene with precise holes drilled in hexagonal patterns. They made the acoustic analogue of twisted bilayer graphene and found the acoustic equivalent of the magic angle. So, as well as twistronics for electrons we now have phononics for sound waves in twisted bilayer graphene, and probably other 2D materials. A new field of scientific study made possible by graphene the progress really is astonishing. The US Government is starting to wake up to the power of graphene. James Tour’s flash graphene is attracting the attention. The team now can take the waste char from plastic recycling and turn it in to graphene that improves the strength of cement by 30%. Rice University says the Air Force Office of Scientific Research and the Department of Energy supported the research. Trade magazines in the construction sector are also picking up on this. Another development by James Tour; Laser induced graphene is being used to make biosensors that detect and diagnose SARS-CoV-2 in blood and saliva samples. The test links to a smartphone and produces results in ten minutes. More work is being done with graphene supercapacitors. It looks like increasing the surface area of graphene nanoplates by increasing the separation between the nanoplates increases the energy density. Cross linking the nanoplates with a big molecule that is also electrically conductive improves the supercapacitor performance still further. Computer graphics card manufacturer, Gigabyte, has launched a new high end gaming card. Graphene is being used to improve the cooling performance, interestingly not using the thermal properties, but using graphene as a lubricant. Investors seem to be taking a more active interest in graphene companies. Ionic, the Australian supercapacitor manufacturer has received $2million to develop its manufacturing operation. In the UK Versarien has raised another £3.5million and Applied Graphene Materials has raised £6million in cash by selling more shares. This gives both companies some financial breathing room but also raises the pressure to deliver revenue growth. And there is lots more of interest in this packed issue. Adrian Nixon, 1st February 2021

Two new graphene companies have appeared on the radar this month. They both use a similar process to make graphene from methane gas with hydrogen as a by-product. Looking at the patents of the companies they both use a microwave reactor to tear apart the carbon and hydrogen atoms in methane, the carbon atoms recombine as graphene and the hydrogen atoms recombine to form hydrogen gas. There the similarities pause because the two companies have very different approaches for how to market their developments. The first company is Levidian, they are a relaunch of Cambridge Nanosystems from the UK. Their business model is focussed on using waste methane gas from a customer’s process. They use the reactor to lock up the carbon in the methane as graphene and claim carbon capture credits. The graphene production is secondary to this marketing approach. Using disclosures by the company, I was able to create a mass balance for the Levidian method. It appears that the process captures carbon from methane with around 30% efficiency (p.34). Not bad, but still some further progress to make. The second company is California based Lyten who publicly disclosed their activity just a few weeks ago. They were formed in 2015 and have been operating in stealth mode. Their graphene is used to make the electrode for a lithium sulphur (LiS) battery that has three times the energy density of normal lithium-ion batteries (p.35). They have probably decided to come out of stealth mode to raise capital for the scaling up of their process. The company is currently talking with five original equipment manufacturers (OEMs) in the automobile industry. The weakness of LiS batteries has been their capacity fade with repeated charge / discharge cycles. Lyten say they have improved on previous LiS designs so they might have something of interest for manufacturers of electric vehicles. Levidian patented their process in 2014 and Lyten in 2015. Lyten references the Levidian patents in their applications. This is how we know the two processes are very similar. Things could get interesting if one or the other company makes a lot of money in the future. As Elon Musk observed “A patent is like buying a lottery ticket to a lawsuit”. Staying with graphene powder manufacture, we feature John van Leeuwen of Universal Matter in a special feature (p.7). He is leading the drive to scale up the flash graphene process developed by Prof James Tour at Rice University. Universal Matter is definitely a company to watch in the future. All these graphene manufacturing processes are bottom-up, self-assembling graphene atom by atom to create high quality powders. These processes are in their infancy at present. If they can be scaled, they could disrupt the graphene-from-graphite manufacturers in future as they promise controllable quality graphene. This potential market disruption is something we’ll explore in the future, in the meantime there is much more to explore in this issue… Adrian Nixon, 1st December 2021